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51.
Zsuzsanna Horváth Judit Sali Andrea Zentai Enikő Dorogházi Zsuzsa Farkas Kata Kerekes 《Journal of environmental science and health. Part. B》2013,48(3):143-152
The pesticide usages are controlled by comparing residue concentrations in treated commodities to legally permitted maximum levels (MRLs) determined based on supervised trials designed to reflect likely maximum residues occurring in practice following authorised use. The number of trials available may significantly affect the accuracy of estimated maximum residues. We conducted a study with synthetic lognormal distributions with mean of 1 and standard deviations of 0.8 and 1.0, which reflect the residue distributions observed in practice. The likely residues in samples were modelled by drawing random samples of size 3, 5, 10 and 25 from the synthetic populations. The results indicate that the estimations of highest residues (HR), used for calculation of short-term intake, and the MRLs, serving as legal limits, are very uncertain based on 3–5 trials indicated by the calculated HR0.975/HR0.025 and MRL0.975/MRL0.025 ratios of 12 and 9, and 13 and 10, respectively, which question the suitability of such trials for the intended purpose. As the 95% range of HR and MRL rapidly decreases with number of trials, ideally ≥15 but minimum 6–8 trials should be used for estimation of HR and MRL according to the current typical practice of Codex Alimentarius. 相似文献
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53.
不同种植方式蔬菜中农药残留的差异及污染控制研究 总被引:1,自引:0,他引:1
采集了陕西地区不同种植方式的瓜果类、叶菜类蔬菜样品,研究了其中各种农药的残留情况,并分析了农药残留对环境的污染及其控制措施。结果表明:露地种植蔬菜与设施种植蔬菜相比,无论是农药残留检出率还是超标率都略高,两者的农药残留检出率分别为42.0%、36.5%,超标率分别为12.0%、8.2%;叶菜类蔬菜与瓜果类蔬菜相比,无论是农药残留检出率还是超标率都较高,两者的农药残留检出率分别为52.6%、29.6%,超标率分别为17.3%、5.4%;设施种植的瓜果类蔬菜和叶菜类蔬菜的农药残留检出率基本接近,而叶菜类蔬菜的农药残留超标率明显高于瓜果类蔬菜,露地种植的叶菜类蔬菜的农药残留检出率和超标率都远高于瓜果类蔬菜;设施种植蔬菜与露地种植蔬菜相比,甲胺磷、对硫磷、甲基对硫磷、毒死蜱、三氟氯氰菊酯和氰戊菊酯的残留检出率更高;瓜果类蔬菜与叶菜类蔬菜相比,毒死蜱、甲氰菊酯、三氟氯氰菊酯、氰戊菊酯的残留检出率更高;叶菜类蔬菜的农药施用浓度较高,施用农药后要间隔一定时间后再上市销售,并应采用更科学的施药方式,以减少农药在蔬菜中的残留和降低对环境的危害;一方面要开发并积极倡导使用高效、低毒、低残留的无公害农药,另一方面则要开发能够高效、快速降解残留农药的物质,同时还要进行农产品的清洁生产,以提高农产品的安全性,并降低环境中农药的残留危害。 相似文献
54.
55.
脱硫灰与钾矿石复合生产钾钙硅镁硫肥料研究 总被引:1,自引:0,他引:1
对脱硫灰与钾矿石复合生产钾钙硅镁硫肥的研究意义、反应原理、生产流程、环境安全性能以及施肥方法等进行了介绍和评估,并对其应用前景进行了展望。研究结果表明:利用脱硫灰与钾矿石复合生产钾钙硅镁硫肥在理论上可行;生产出的产品中硫酸钾的含量达10.34%~12.0%,枸溶氧化钙19.06%~32.28%,枸溶二氧化硅10.98%~14.46%,枸溶氧化镁1.46%~1.82%。产品的pH值从原脱硫灰的10.65下降到9.60。重金属含量低于农用粉煤灰国家标准,生产过程中不会产生SO2等有害气体污染。肥料的生产成本低于350元/t,该肥料不但可以增加土壤中钾、钙、硅、镁和硫等中微量元素的含量,而且可以提高或改善农作物的产量和品质。达到变废为宝,促进循环经济发展之目的。 相似文献
56.
本文对用硫法锂渣制取白炭黑的基本原理及工艺流程作了较为详细的阐述,对该工艺的各种影响因素进行了探讨,并制得了合格的白炭黑,为锂渣的综合利用开辟了新的途径。 相似文献
57.
W. L. Nutter T. Tkacs P. B. Bush D. G. Neary 《Journal of the American Water Resources Association》1984,20(6):851-858
The breakpoint rainfall hydrology and pesticide options of the field scale model CREAMS (Chemicals, Runoff, and Erosion from Agricultural Management Systems) were used to predict average concentrations of hexazinone [3 cyclohexyl-6-(dimethyl-amino)-1-methyl-1,3,5-triazine-2,4(1H,3H)-dione] in stormflow from four forested watersheds in the upper Piedmont region of Georgia. Predicted concentrations were compared with measured concentrations recorded over a 13-month period. CREAMS accurately predicted hexazinone concetrations in the initial stormflow events which also contained the highest concentrations. The model underestimated the hexazinone concentrations in stormflow two months and greater following pesticide application. In a companion study, the daily rainfall option of the CREAMS model was used to evaluate the reltive risk associated with the maximum expected concentration of hexazinone, bromacil (5-bromo-3 sec-butyl-6 methyuracil), picloram (4-amino-3,5,6 trichloropicolinic acid), dicamba (3,6-dichloro-0-anisic acid), and triclopyr {[(3,5,6-trichloro-2-pyridinyl)oxy] acetic acid} in stormflow from small forested watersheds. The model predicted the following order of potential residue appearance in stormflow: bromacil>triclopyr>hexazinone>picloram>dicamba. Subsurface movement of residues via interflow and deep leaching losses are not simulated by the version of CREAMS used in these studies. 相似文献
58.
Holger Ecke Nourreddine Menad Anders Lagerkvist 《Journal of Material Cycles and Waste Management》2002,4(2):117-126
Dry scrubber residue from municipal solid waste incineration (MSWI) was characterized to identify critical inorganic pollutants
and to suggest a conceptual treatment method. The key methods used were thermal analysis, including thermogravimetry (TG)
and differential thermal analysis (DTA), pHstat titration, qualitative X-ray diffraction (XRD), scanning electron microscopy (SEM), chemical equilibrium calculations, and
statistics such as error propagation, principal component analysis (PCA), and empirical modeling based on factorial designs.
Based on EU directives, the major inorganic pollutants Cd, Cr, Pb, and Zn were found. In addition, the pH was too high. With
dry scrubber residue stabilization in mind, the impact of carbonation and hydration was assessed and judged to be encouraging.
In particular, chemical equilibrium calculations showed that carbonation has considerable potential to lower the pH and the
availability of Pb, Zn, and Cr. The impact of carbonation on the mobility of Cd was found to be small. During carbonation,
a metal-trapping calcium aluminosilicate hydrate (C–A–S–H) phase is also formed. Both processes together have the potential
to lead to a robust, reliable, and reasonable stabilization method for dry scrubber residue. However, to control these processes,
the decisive factors need to be identified and their effects need to be quantified. Ca, Cl, Na, and K might be abundant components
which would be mobile even after stabilization.
Received: September 11, 2001 / Accepted: December 6, 2001 相似文献
59.
60.
Status of recycling end-of-life vehicles and efforts to reduce automobile shredder residues in Korea
Hyun-Tae Joung Sung-Jin Cho Yong-Chil Seo Woo-Hyun Kim 《Journal of Material Cycles and Waste Management》2007,9(2):159-166
The present end-of-life vehicle (ELV) recycle rate and management status during the dismantling stage were investigated to
aid the establishment of policies for the management of ELVs by surveying information and using the results gained from questionnaires
given to dismantlers. The average recycle rate at the dismantling stage was 44% of the mass of a new vehicle and the rest
of the ELV was then compressed and transported to shredding companies to recover mainly the iron content, which averaged 38.7%
of the mass of a new vehicle. Nonferrous metals such as copper, antimony, zinc, and aluminum accounted for only 1.5%. The
automobile shredder residues (ASRs) were composed of light and heavy fluffs and soil/dust and amounted to 15.8% based on the
mass of a new vehicle. The dumping of fluff and inorganic residues in landfill sites, however, will be restricted when new
regulations are implemented to reduce the disposal amount to less than 5% of a new car, as has been done in European countries
and in Japan. The detailed characteristics of ASR were investigated to suggest appropriate means of treatment such as volume
reduction or the utilization of thermal technologies to meet future expected enforcement. Also, some concerns on hazardous
pollutant release such as that of dioxins while utilizing such thermal treatment methods were considered. The present on-going
research and development projects to meet such future management targets are also introduced. 相似文献